Nanofluidics
is the study of the behavior, manipulation, and control of fluids that are
confined to structures of nanometer
(typically 1-100 nm) characteristic dimensions (1 nm = 10-9 m). Fluids
confined in these structures exhibit physical behaviors not observed in
larger structures, such as those of micrometer dimensions and above, because
the characteristic physical scaling lengths of the fluid, (e.g. Debye length,
hydrodynamic radius) very closely coincide with the dimensions of the nanostructure itself. When structures approach
the size regime corresponding to molecular
scaling lengths, new physical constraints are placed on the behavior of the
fluid. For example, these physical constraints induce regions of the fluid to
exhibit new properties not observed in bulk, e.g. Vastly increased viscosity near the pore wall; they may effect
changes in thermodynamic properties and may also alter the chemical
reactivity of species
at the fluid-solid interface.
A particularly relevant and useful example is displayed by electrolyte
solutions confined in nanopores
that contain surface charges, i.e. At electrified interfaces,
as shown in the nanocapillary array membrane
(NCAM) in the accompanying figure.
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