Strain

 

In mechanical engineering, strain is a measure of the deformation resulting from stress (that is, force per unit area); the displacement of one point with respect to another, divided by their equilibrium separation in the absence of stress. In chemistry, a molecular fragment generally has some equilibrium geometry (bond lengths, interbond angles, etc.) When the rest of the molecular structure does not impose special constraints (e.g., bending bonds to form a small ring). Deviations from this equilibrium geometry are described as strain, and increase the energy of the molecule. Strain in the mechanical engineering sense causes strain in the chemical sense.

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